EVALUATION OF THE USE OF LITHIUM COMPOUNDS IN CONTROLLING ALKALI-SILICA REACTIVITY IN EXISTING CONCRETE STRUCTURES

ABSTRACT

BACKGROUND

 

Lithium Project  

 
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Abstract

 

        For FY 2000, the Federal Highway Administration (FHWA) was directed by Congress to fund a program of research and implementation of lithium-based technologies for the mitigation of alkali-silica reactivity (ASR) in Portland cement concrete. Two types of field trials will be considered: (1) New construction or reconstruction projects using lithium-based technologies to prevent ASR, and (2) Application of lithium-based technologies on existing concrete to mitigate ASR. The objective of these field trial studies is to demonstrate the use of lithium-based technologies to (DOT) agencies and to document field performance of these technologies.
ASR takes place between certain reactive siliceous aggregates (e.g., opal, chalcedony and volcanic glass) and the alkali from Portland cement paste or external source. A reaction product gel forms that, in the presence of water, expands and may cause cracking of mortar and concrete. These surface cracks are aggravated by winter deicing salts and freeze-thaw action, leading to shallow delamination, rebar corrosion, potholes, and other serious problems including structural failure. Recent studies have shown that adding lithium compounds to concrete in the plastic state to be effective in the control of ASR.
However, lithium-based technology has not been widely applied to existing and aged concrete bridge decks and pavements. The development of materials and application procedures is urgently needed for field implementation using lithium compounds in arresting ASR in existing concrete pavements.
       A stretch of N. first Street in Norfolk, Nebraska, has been selected for lithium treatment. The 8-year old concrete pavement is 8 inches in thickness. Originally constructed in 1995. This project is proposed to be a joint effort of Nebraska Department of Roads (NDOR), the U.S.Army Corps of Engineers, Omaha District (USACE), and the University of Nebraska-Lincoln (UNL), in that the project will be managed by NDOR, in-situ testing and petrographic examinations of lithium-treated and untreated concrete samples will be performed by USACE, laboratory testing will be conducted at UNL, and the lithium treatment procedures will be jointly developed by the research team.

sponsored by: Federal Highway Administration (FHWA/HIPT)Lithium Field Implementation